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19 Questions around this concept.
Sugar which does not give reddish brown precipitate with Fehling's reagent is :
Molisch's Test
A drop of alcoholic solution of -Naphthol is added in 2ml of carbohydrate solution and 1ml of conc.H2SO4 is added carefully along the side of the tube. The formation of violet ring at the junction of 2-liquids shows the presence of carbohydrate.
Molisch’s test is a general test for all carbohydrates. In this test, carbohydrates when reacted with conc. H2SO4 get dehydrated to form furfural and its derivatives. When monosaccharide are treated with conc. H2SO4 or conc. HCl, -OH group of sugar are removed in the form of water and furfural is formed from pentose sugar and hydroxymethyl furfural is formed from hexose sugar. These products react with sulphonated α- naphthol to give a purple (violet-red) coloured complex.
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