Section 1: Chemistry of High Polymers | Monomers, functionality, degree of polymerizations, classification of polymers, glass transition, melting transition, criteria for rubberiness, polymerization methods: addition and condensation; their kinetics, metallocene polymers and other newer methods of polymerization, copolymerization, monomer reactivity ratios and its significance, kinetics, different copolymers, random, alternating, azeotropic copolymerization, block and graft copolymers, techniques for polymerization-bulk, solution, suspension, emulsion. Concept of intermolecular order (morphology) – amorphous, crystalline, orientation states. Factor affecting crystallinity. Crystalline transition. Effect of morphology on polymer properties. |
Section 2: Polymer Characterization | Solubility and swelling, Concept of molecular weight distribution and its significance, concept of average molecular weight, determination of number average, weight average, viscosity average and Z-average molecular weights, polymer crystallinity, analysis of polymers using IR, XRD, thermal (DSC, DMTA, TGA), microscopic (optical and electronic) techniques, Molecular wt. distribution: Broad and Narrow, GPC, Mooney viscosity. |
Section 3: Synthesis, Manufacturing and Properties | Commodity and general purpose thermoplastics: PE, PP, PS, PVC, Polyesters, Acrylic, PU polymers. Engineering Plastics: Nylon, PC, PBT, PSU, PPO, ABS, Fluoropolymers Thermosetting polymers: Polyurethane, PF, MF, UF, Epoxy, Unsaturated polyester, Alkyds. Natural and synthetic rubbers: Recovery of NR hydrocarbon from latex; SBR, Nitrile, CR, CSM, EPDM, IIR, BR, Silicone, TPE, Speciality plastics: PEK, PEEK, PPS, PSU, PES, etc. Biopolymers such as PLA, PHA/PHB. |
Section 4: Polymer Blends and Composites | Difference between blends and composites, their significance, choice of polymers for blending, blend miscibility-miscible and immiscible blends, thermodynamics, phase morphology, polymer alloys, polymer eutectics, plastic-plastic, rubber-plastic and rubber-rubber blends, FRP, particulate, long and short fibre reinforced composites. Polymer reinforcement, reinforcing fibres – natural and synthetic, base polymer for reinforcement (unsaturated polyester), ingredients/recipes for reinforced polymer composite. |
Section 5: Polymer Technology | Polymer compounding-need and significance, different compounding ingredients for rubber and plastics (Antioxidants, Light stabilizers, UV stabilizers, Lubricants, Processing aids, Impact modifiers, Flame retardant, antistatic agents, PVC stabilizers, and Plasticizers) and their function, use of carbonblack, polymer mixing equipments, cross-linking and vulcanization, vulcanization kinetics. |
Section 6: Polymer Rheology | Flow of Newtonian and non-Newtonian fluids, different flow equations, dependence of shear modulus on temperature, molecular/segmental deformations at different zones and transitions. Measurements of rheological parameters by capillary, rotating, parallel plate, cone-plate rheometer. Visco-elasticity-creep and stress relaxations, mechanical models, control of rheological characteristics through compounding, rubber curing in parallel plate viscometer, ODR and MDR. |
Section 7: Polymer Processing | Compression molding, transfer molding, injection molding, blow molding, reaction injection molding, filament winding, SMC, BMC, DMC, extrusion, pultrusion, calendaring, rotational molding, thermoforming, powder coating, rubber processing in two-roll mill, internal mixer, twin screw extruder.
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Section 8: Polymer Testing. | Mechanical-static and dynamic tensile, flexural, compressive, abrasion, endurance, fatigue, hardness, tear, resilience, impact, toughness. Conductivity-thermal and electrical, dielectric constant, dissipation factor, power factor, electric resistance, surface resistivity, volume resistivity, swelling, ageing resistance, environmental stress cracking resistance, limiting oxygen index. Heat deflection temperature – Vicat softening temperature, Brittleness temperature, Glass transition temperature, Co-efficient of thermal expansion, Shrinkage, Flammability, dielectric constant, dissipation factor, power factor, Optical Properties - Refractive Index, Luminous Transmittance and Haze, Melt flow index |
Section 9: Polymer Recycling and Waste Management | Polymer waste, and its impact on environment, Sources, Identification and Separation techniques, recycling classification, recycling of thermoplastics, thermosets and rubbers, applications of recycled materials. Life cycle assessment of polymer products (case studies like PET bottles, packaging bags). |
