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Ideal gas equation is considered one of the most asked concept.
48 Questions around this concept.
Which of the following shows the correct relationship between the pressure ‘P’ and density ρ of an ideal gas at constant temperature ?
‘n’ moles of an ideal gas undergoes a process A→B as shown in the figure. The maximum temperature of the gas during the process will be :
The equation which relates the pressure (P), volume (V) and temperature (T) of the given state of an ideal gas is known as an ideal gas equation or equation of state.
From Boyle's law, we get
$
V \propto \frac{1}{P}
$
and From Charle's Law, we get $V \propto T$.
And from Avogadro's Law, we get $V \propto n$
And from equation (1), (2), (3)
we can write
$
\begin{aligned}
& V \propto \frac{n T}{P} \\
& \text { or } \frac{P V}{n T}=\text { constant } \\
& \text { or } \frac{P V}{n T}=R(\text { where } R \text { is proportionality constant }) \\
& \text { or } P V=n R T
\end{aligned}
$
So Ideal Gas Equation is given as
$
P V=n R T
$
where
T= Temperature
P= pressure of ideal gas
V= volume
n= numbers of mole
R = universal gas constant
At S.T.P. the value of the universal gas constant is the same for all gases.
And its value is given as
$
R=8.31 \frac{\text { Joule }}{\text { mole } \times \text { Kelvin }}=2 \frac{\mathrm{cal}}{\text { mole } \times \text { Kelvin }}
$
And its Dimension is : $\left[M L^2 T^{-2} \theta^{-1}\right]$
- Boltzman's constant (k)-
It is represented by per mole gas constant.
$
\text { i.e } k=\frac{R}{N}=\frac{8.31}{6.023 \times 10^{23}}=1.38 \times 10^{-23} \mathrm{~J} / \mathrm{K}
$
- Specific gas constant (r)-
It is represented by per gram gas constant.
i.e. $\quad r=\frac{R}{M}$
It's unit is $\frac{\text { Joule }}{\mathrm{gm} \times \text { kelvin }}$
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