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Classification of Elements and Periodicity in Properties - Practice Questions & MCQ

Edited By admin | Updated on Sep 18, 2023 18:34 AM | #JEE Main

Quick Facts

  • Classification of Elements : s-block is considered one of the most asked concept.

  • 40 Questions around this concept.

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Element not showing variable oxidation state is :

Concepts Covered - 4

Classification of Elements : s-block
  • The elements having ns1 and ns2 electronic configurations in their outermost shell are called s-block elements. 

  • Elements with ns1 configuration are called group 1 (alkali elements). 

  • Elements with ns2 configuration are called group 2 (alkaline earth elements).

  • They are highly reactive and readily form univalent or bivalent positive ions by losing the valence electrons.

  • The elements of this block are soft, malleable and good conductors of heat and electricity. 

  • The elements have largest atomic and ionic radii but lowest ionization energies. 

  • They show fix valency and oxidation states. 

  • The loss of the outermost electrons(s) occurs readily to form M+ (in case of alkali metals) or M2+ ions (in case of alkaline earth elements). 

  • Except beryllium compounds all other compounds of this block elements are predominantly ionic.

  • They are soft metals having low melting points and boiling points. 

  • These metals and their salts impart characteristic colour to the flame. For example, sodium salt imparts a golden yellow colour to flame. 

  • The elements of this group have large size, strong reducing nature, high electropositive nature, very low electronegativity values, ionization energy and electron affinity. 

Classification of Elements : p-block
  • The elements whose last electron enters into any p-orbital are known as p-block elements. 

  • The general outer electronic configuration for these elements is ns2np1-6.

  • Group 13 or III A have one electron in p-orbital whereas group 18 or VIII A (inert gas) have 6 electrons in their outer p-orbitals. The outer p-orbitals in an inert gas are fully-filled with electrons. 

  • They include both metals and nonmetals but there is a regular change from metallic to non-metallic character as we move from left to right across the period. 

  • These elements do not impart colour to the flame test.

  • Except F and inert gases, all other elements of this block show variable oxidation states. 

  • They have quite high ionization energies and the values tend to increase as we move from left to right across the period.

  • They form covalent compounds mostly like oxides, halides, sulphides, carbonates, etc. 

  • Except metals, the other elements of this block are nonconductors. 

  • A number of elements of this block show catenation property and allotropy like C, Si, Ge,  S, O etc.

  • As we move from left to right, there is a gradation from reducing to oxidizing properties.

Classification of Elements : d-block
  • The d-block is in between s and p blocks. In these elements, their last electron enters into any of the d-orbitals. These elements are also known as transition elements as their properties are in between s and p-block elements. 

  • The general electronic configuration of d-block elements is (n-1)d1-10ns1-2.

  • These elements are in between 2-13 group in the periodic table.

  • They show variable valency and oxidation state in their chemical bond formation.

  • These metals have high values of melting points, boiling points, densities, thermal stability and hardness. 

  • They are ductile and malleable. 

  • They are good conductors of heat and electricity due to the presence of free electron.

  • They form coloured ions and complexes.

  • Metals and their ions are generally paramagnetic in nature because of the presence of unpaired electrons.

  • These metals form a number of alloys as they have almost similar sizes. 

  • These metals and their compounds are widely used as catalysts. 

  • These metals also form nonstoichiometric and interstitial compounds with small size atoms like H, C, N, O which can be easily fitted in the vacant sides of the lattices of these metals. For example, Fe0.93O.

Classification of Elements : f-block
  • The elements placed in two separate rows at the bottom of the periodic table are f-block elements.

  • These elements have their last electron enters into the f-orbital.

  • The elements from cerium to lutetium having incomplete 4f-orbitals are known as lanthanoids.

  • The elements from thorium to lawrencium having incomplete 5f-orbitals are known as actinides. 

  • The general electronic configuration of f-block elements is (n-2)f1-14(n-1)d1-2ns2.

  • Many of actinide elements have been made only in nanogram quantities or less by nuclear reactions and their chemistry is not fully studied. 

  • Many of them are synthetic elements. 

  • The elements coming after uranium are called transuranium elements. 

  • They are metals having high melting and boiling points. 

  • They show variable oxidation states however their most common and stable oxidation state is +3.

  • They form coloured ions and complexes. 

  • Actinides are radioactive in nature.​​​​​​

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Classification of Elements : s-block
Classification of Elements : p-block
Classification of Elements : d-block

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Books

Reference Books

Classification of Elements : s-block

Chemistry Part I Textbook for Class XI

Page No. : 83

Line : 40

Classification of Elements : p-block

Chemistry Part I Textbook for Class XI

Page No. : 85

Line : 11

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