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Radius, velocity and the energy of nth Bohr orbital is considered one the most difficult concept.
43 Questions around this concept.
Which of the following statements in relation to the hydrogen atom is correct?
Energy of an electron is given by ,Wavelength of light required to excite an electron in a hydrogen atom from level n = 1 to n = 2 will be:
(h=6.6210-34Js and c = 3.0 108 ms-1)
If m and e are the mass and charge of the revolving electron in the orbit of radius r for hydrogen atom, the total energy of the
revolving electron will be :
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Given below are two statements :
Statement (I) : The orbitals having same energy are called as degenerate orbitals.
Statement (II) : In hydrogen atom, 3p and 3d orbitals are not degenerate orbitals.
In the light of the above statements, choose the most appropriate answer from the options given below :
Bohr's model and its postulates:
1. The electron in the hydrogen atom can move around the nucleus in a circular path of fixed radius and energy. These paths are called orbits, stationary states or allowed energy states and are arranged concentrically around the nucleus. Force of attraction between the nucleus and an electron provides the centripetal force required by the electron to carry out the circular motion.
2. The energy of an electron in the orbit does not change with time. However, the electron will move from a lower stationary state to a higher stationary state when required amount of energy is absorbed by the electron or energy is emitted when electron moves from higher stationary state to lower stationary state
3. Energy can be absorbed or emitted when electron transitions between two different orbits and the frequency of photon involved can be calculated using the formula:
4. The angular momentum of an electron is quantised. In a given stationary state it can be expressed as
L= mvr= nh/2, n = orbit number
So only those energy states (or orbits) are allowed in which the above equation holds true for the angular momentum.
Note: Bohr's model is only valid for Hydrogen like species or unielectronic species which contain only a single electron
According to Bohr’s theory for hydrogen atom:
(1) The stationary states for electron are numbered n = 1,2,3.......... These integral numbers are known as Principal quantum numbers.
(2) Bohr radius of nth orbit:
where Z is atomic number and radius is calculated by the formula in angstrom (A0) (1A0=10-10 m)
(3) Velocity of electron in nth orbit:
where Z is atomic number
(4) Total energy of electron in nth orbit:
where Z is atomic number
Depending upon the units given in the question, the respective formula can be used
(5) Time Period and Frequency of Revolution
Although the precise equations for time period and frequency of revolution are not required but still it is a good idea to look at the variations of these with the atomic number (Z) and the orbit number (n).
We know that Time period (T) is the time required for one complete revolution and that Frequency () is inverse of the time period
It is important that you remember all the above formula and relations
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