VIT - VITEEE 2025
National level exam conducted by VIT University, Vellore | Ranked #11 by NIRF for Engg. | NAAC A++ Accredited | Last Date to Apply: 31st March | NO Further Extensions!
Pi (p-p) and Pi (p-d) bonding is considered one of the most asked concept.
21 Questions around this concept.
The number and type of bonds in ion in CaC2 are :
How many $p \pi-p \pi$ and $p \pi-d \pi$ bonds are present in $\mathrm{SO}_3$ ?
In XeO3F2 , the number of bond pair(s), $\pi$-bond(s) and lone pair(s) on Xe atom respectively are :
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Among the oxides of nitrogen : $\mathrm{N}_2 \mathrm{O}_{3,} \mathrm{~N}_2 \mathrm{O}_4$ and $\mathrm{N}_2 \mathrm{O}_5$ ; the molecule(s) having nitrogen-nitrogen bond is/are :
Number of $\sigma$ and $\pi$ bonds in P4O10 molecule respectively
the correct order of bond strength is =
In forming (i) $\mathrm{N}_2 \rightarrow \mathrm{N}_2^{+}$ and (ii) $\mathrm{O}_2 \rightarrow \mathrm{O}_2^{+}$; the electrons respectively are removed from:
National level exam conducted by VIT University, Vellore | Ranked #11 by NIRF for Engg. | NAAC A++ Accredited | Last Date to Apply: 31st March | NO Further Extensions!
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$p \pi-p \pi$ multiple bonds occur between
$p \pi-p \pi$ Bonding
When one p-orbital of one atom contains one electron and the other atom also has one electron in the p orbirtal , both perpendiculat to the plane of the molecule then the type of bond formed is known as $p \pi-p \pi$ bonding.
$p \pi-d \pi$ Bonding
When one p-orbital of one atom contains one electron and the other atom also has one electron then the type of bond formed is known as $p \pi-p \pi$ bonding. In other words, $p \pi-d \pi$ bond is formed when p orbital of one atom and d orbital of another atom overlap laterally.
For example, PO43- has a $p \pi-d \pi$ bonding because the lateral overlap of p-orbital of oxygen atom with d-orbital of sulphur atom occurs.
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