JEE Main 2025 April 2 Exam Analysis: Paper Difficulty Level and Topics

Pi Bonds - Practice Questions & MCQ

Edited By admin | Updated on Sep 18, 2023 18:35 AM | #JEE Main

Quick Facts

  • Pi (p-p) and Pi (p-d) bonding is considered one of the most asked concept.

  • 21 Questions around this concept.

Solve by difficulty

The number and type of bonds in \mathrm{C_{2}^{2-}} ion in CaC2 are :

How many $p \pi-p \pi$ and $p \pi-d \pi$ bonds are present in $\mathrm{SO}_3$ ?

In XeO3F2 , the number of bond pair(s), $\pi$-bond(s) and lone pair(s) on Xe atom respectively are :

Among the oxides of nitrogen : $\mathrm{N}_2 \mathrm{O}_{3,} \mathrm{~N}_2 \mathrm{O}_4$ and $\mathrm{N}_2 \mathrm{O}_5$ ; the molecule(s) having nitrogen-nitrogen bond is/are :

Number of $\sigma$ and $\pi$ bonds in P4O10 molecule respectively

the correct order of bond strength is =

In forming (i) $\mathrm{N}_2 \rightarrow \mathrm{N}_2^{+}$ and (ii) $\mathrm{O}_2 \rightarrow \mathrm{O}_2^{+}$; the electrons respectively are removed from:

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$p \pi-p \pi$ multiple bonds occur between

Concepts Covered - 1

Pi (p-p) and Pi (p-d) bonding

$p \pi-p \pi$ Bonding

When one p-orbital of one atom contains one electron and the other atom also has one electron in the p orbirtal , both perpendiculat to the plane of the molecule  then the type of bond formed is known as $p \pi-p \pi$ bonding.  

 

$p \pi-d \pi$ Bonding

When one p-orbital of one atom contains one electron and the other atom also has one electron then the type of bond formed is known as $p \pi-p \pi$ bonding. In other words, $p \pi-d \pi$ bond is formed when p orbital of one atom and d orbital of another atom overlap laterally.

For example, PO43- has a $p \pi-d \pi$ bonding because the lateral overlap of p-orbital of oxygen atom with d-orbital of sulphur atom occurs.

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Pi (p-p) and Pi (p-d) bonding

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Pi (p-p) and Pi (p-d) bonding

Chemistry Part I Textbook for Class XI

Page No. : 119

Line : 20

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