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Energy Level Diagram - Practice Questions & MCQ

Edited By admin | Updated on Sep 18, 2023 18:35 AM | #JEE Main

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  • 32 Questions around this concept.

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 Which one of the following molecules is paramagnetic ?

Which one of the following species is diamagnetic in nature?

Which one of the following pairs of species have the same bond order?

Which of the following species is not paramagnetic ?

The bond order in  NO is 2.5 while that in NO+ is 3.  Which of the following statements is true for these two species?

Which of the following species exhibits the diamagnetic behaviour?

Using MO theory predict which of the following species has the shortest bond length ?

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Which of the following molecules/ ions does not contain unpaired electrons?

The bond order and magnetic property of acetylide ion are same as that of:

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Concepts Covered - 1

Energy Level Diagram for Molecules

Molecular Orbital Energy Diagrams

The relative energy levels of atomic and molecular orbitals are typically shown in a molecular orbital diagram. As given in the figure below, for a diatomic molecule, the atomic orbitals of one atom are shown on the left, and those of the other atom is shown on the right. Each horizontal line represents one orbital that can hold two electrons. The molecular orbitals formed by the combination of the atomic orbitals are shown in the center. Dashed lines show which of the atomic orbitals combine to form the molecular orbitals. For each pair of atomic orbitals that combine, one lower-energy (bonding) molecular orbital and one higher-energy (antibonding) orbital result. Thus we can see that combining the six 2p atomic orbitals results in three bonding orbitals (one σ and two π) and three antibonding orbitals (one σ* and two π*).

22A diagram is shown that has an upward-facing vertical arrow running along the left side labeled, “E.” At the bottom center of the diagram is a horizontal line labeled, “sigma subscript 2 s,” that has two vertical half arrows drawn on it, one facing up and one facing down. This line is connected to the right and left by upward-facing, dotted lines to two more horizontal lines, each labeled, “2 s.” The line on the left has two vertical half arrows drawn on it, one facing up and one facing down while the line of the right has one half arrow facing up drawn on it. These two lines are connected by upward-facing dotted lines to another line in the center of the diagram, but further up from the first. It is labeled, “sigma subscript 2 s superscript asterisk.” This horizontal line has one upward-facing vertical half-arrow drawn on it. Moving farther up the center of the diagram is a long horizontal line labeled, “sigma subscript 2 p subscript x,” which lies below two horizontal lines. These two horizontal lines lie side-by-side, and labeled, “pi subscript 2 p subscript y,” and, “pi subscript 2 p subscript z.” Both the bottom and top lines are connected to the right and left by upward-facing, dotted lines to three more horizontal lines, each labeled, “2 p.” These sets of lines are connected by upward-facing dotted lines to another single line and then pair of double lines in the center of the diagram, but farther up from the lower lines. They are labeled, “sigma subscript 2 p subscript x superscript asterisk,” and, ““pi subscript 2 p subscript y superscript asterisk,” and, “pi subscript 2 p subscript z superscript asterisk,” respectively. The left and right sides of the diagram have headers that read, ”Atomic orbitals,” while the center is header reads “Molecular orbitals”.

molecular orbital diagram 

 

The molecular orbitals are filled in the same manner as atomic orbitals, using the Aufbau principle and Hund’s rule.

 

Bond Order

The filled molecular orbital diagram shows the number of electrons in both bonding and antibonding molecular orbitals. The net contribution of the electrons to the bond strength of a molecule is identified by determining the bond order that results from the filling of the molecular orbitals by electrons.

The MO technique is more accurate and can handle cases when the Lewis structure method fails, but both methods describe the same phenomenon.

In the molecular orbital model, an electron contributes to a bonding interaction if it occupies a bonding orbital and it contributes to an antibonding interaction if it occupies an antibonding orbital. The bond order is calculated by subtracting the destabilizing (antibonding) electrons from the stabilizing (bonding) electrons. Since a bond consists of two electrons, we divide by two to get the bond order. We can determine bond order with the following equation:

bond order = [(number of bonding electrons)−(number of antibonding electrons)]/2

The order of a covalent bond is a guide to its strength; a bond between two given atoms becomes stronger as the bond order increases. If the distribution of electrons in the molecular orbitals between two atoms is such that the resulting bond would have a bond order of zero, a stable bond does not form. 

 

For example, the bond order of H2 molecule is given as follows:

A diagram is shown that has an upward-facing vertical arrow running along the left side labeled “E.” At the bottom center of the diagram is a horizontal line labeled, “sigma subscript 1 s,” that has two vertical half arrows drawn on it, one facing up and one facing down. This line is connected to the right and left by upward-facing, dotted lines to two more horizontal lines, each labeled, “1 s,” and each with one vertical half-arrow facing up drawn on it. These two lines are connected by upward-facing dotted lines to another line in the center of the diagram, but farther up from the first, and labeled, “sigma subscript 1 s superscript asterisk.” The left and right sides of the diagram have headers that read, ”Atomic orbitals,” while the center header reads, “Molecular orbitals.” The bottom left and right are labeled “H” while the center is labeled “H subscript 2.”

The molecular orbital energy diagram predicts that H2 will be a stable molecule with lower energy than the separated atoms.

 

A dihydrogen molecule contains two bonding electrons and no antibonding electrons so we have:

bond order in H2=(2−0)/2=1

Because the bond order for the H–H bond is equal to 1, the bond is a single bond.

 

Magnetic Moment

The magnetic behaviour of any molecule can be determined from the number of unpaired electrons in the bonding and antibonding orbitals. The molecule is said to be diamagnetic as there is no unpaired electron present in the orbitals and not attracted by the magnet. But if any unpaired electron is present then the molecule is paramagnetic.

For example, O2 molecule has 2 unpaired electrons can be seen from the diagram below:

Therefore, O2 molecule is paramagnetic.

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Energy Level Diagram for Molecules

Chemistry Part I Textbook for Class XI

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