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Bleaching Powder - Practice Questions & MCQ

Edited By admin | Updated on Sep 18, 2023 18:35 AM | #JEE Main

Quick Facts

  • 4 Questions around this concept.

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Bleaching Powder

Preparation

  • It is a mixture of CaCl2 and Ca(OCl)2.
  • It is manufactured in Bachmann's plant.
  • The chemical reaction for the preparation of bleaching powder is as follows:
    \mathrm{Ca(OH)_{2}\: +\: Cl_{2}\: \rightarrow CaOCl_{2}\: +\: H_{2}O}

Physical properties

  • It is yellowish-white powder with smell of chlorine.
  • Most of it is soluble in water but small amount is insoluble in lime.

Chemical properties

  • Reaction with insufficient and excess dilute acid:
    \mathrm{CaOCl_{2}\: +\: H_{2}SO_{4}\: \rightarrow CaSO_{4}\: +\: CaCl_{2}\: +\: 2HCl\: +\: O_{2}}
  • Autoxidation: When it undergoes autoxidation, it loses its available chlorine due to which it affects its bleaching process.
    \mathrm{6CaOCl_{2}\: \rightarrow 5CaCl_{2}\:+\: Ca(ClO_{3})_{2}}
  • Catalytic decomposition: The catalytic decomposition of bleaching powder occurs as follows:
    \mathrm{2CaOCl_{2}\: \overset{CoCl_{2}}{\longrightarrow}2CaCl_{2}\:+\: O_{2}}

Uses

  • It is an oxidising agent.
  • It is a chlorinating agent.
  • It is used as a disinfectant.
  • It sterilizes water. 

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